Electron paramagnetic resonance analysis of dimethyl amidogen in polycrystalline tetramethyl tetrazene.
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Authors
Eikel, Harvey Andrew.
Subjects
dimethyl amidogen
electron paramagnetic resonance
polycrystalline spectrum analysis
tetramethyl tetrazene
electron paramagnetic resonance
polycrystalline spectrum analysis
tetramethyl tetrazene
Advisors
Tolles, William M.
Date of Issue
1966-05
Date
May 1966
Publisher
Monterey, California: U.S. Naval Postgraduate School
Language
en_US
Abstract
The photolytic decomposition of tetramethyl-2-tetrazene yields a short-lived paramagnetic species which is stabilized at liquid nitrogen temperatures. For the analysis of the electron paramagnetic resonance spectrum the species has been identified as the free radical dimethyl amidogen. The hyperfine coupling tensors were assigned on the basis of a polycrystalline line shape analysis. The radical exhibits axial symmetry with the parallel components of the tensors greater than the perpendicular components. The limits of error associated with the components of the tensors were estimated from the general comparison of the calculated and observed spectra.
Type
Thesis
Description
Series/Report No
Department
Chemistry
Organization
Naval Postgraduate School (U.S.)
Identifiers
NPS Report Number
Sponsors
Funder
Format
Citation
Distribution Statement
Approved for public release; distribution is unlimited.
Rights
This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.