The kinetics of successive aquation reactions of tetraamminepalladium (II) ion
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Authors
DeBerry, William Jennings, Jr.
Subjects
Tetraamminepalladium (II) ion
Tetraaquopalladium (II) ion
Tetraaquopalladium (II) ion
Advisors
Reinhardt, Richard A.
Date of Issue
1971-06
Date
June 1971
Publisher
Monterey, California; Naval Postgraduate School
Language
en_US
Abstract
Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed.
Type
Thesis
Description
Series/Report No
Department
Department of Chemistry
Organization
Naval Postgraduate School (U.S.)
Identifiers
NPS Report Number
Sponsors
Funder
Format
Citation
Distribution Statement
Approved for public release; distribution is unlimited.
Rights
This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.