Mono- and diioso-1,2,3-trizoles and their mono nitro derivatives
| dc.contributor.author | Chand, Deepak | |
| dc.contributor.author | He, Chunlin | |
| dc.contributor.author | Hooper, Joseph P. | |
| dc.contributor.author | Mitchell, Lauren A. | |
| dc.contributor.author | Parrish, Damon A. | |
| dc.contributor.author | Shreeve, Jean'ne M. | |
| dc.contributor.corporate | Naval Postgraduate School (U.S.) | en_US |
| dc.contributor.department | Physics | en_US |
| dc.date.accessioned | 2017-02-15T15:37:18Z | |
| dc.date.available | 2017-02-15T15:37:18Z | |
| dc.date.issued | 2016 | |
| dc.description | The article of record as published may be found at http://dx.doi.org/10.1039/c6dt01731b | en_US |
| dc.description.abstract | 4-Iodo-1H-1,2,3-triazole (2) and 4,5-diiodo-1H-1,2,3-triazole (3) were synthesized using an efficient and viable synthetic route. The N-alkylation of 3 resulted in the formation of two tautomers. The N-alkyldiiodo- triazoles were nitrated with 100% nitric acid to form monoiodo–mononitro-triazoles. The structures of 2-methyl-4,5-diiodo-1,2,3-triazole (5), 1-ethyl-4,5-diiodo-1,2,3-triazole (6), 1-methyl-4-nitro- 5-iodo-1,2,3-triazole (8) and 1-ethyl-4-nitro-5-iodo-1,2,3-triazole (10) were confirmed by X-ray crystal analysis. All of the new triazoles were fully characterized via NMR, and infrared spectra, and elemental analyses as well as by their thermal and sensitivity properties. Decomposition products calculated using Cheetah 7 software show that these iodo–nitro triazoles liberate iodine. | en_US |
| dc.description.funder | N00014-16-1-2089 (ONR) | |
| dc.description.funder | HDTRA 1-15-1-0028 | |
| dc.description.sponsorship | Office of Naval Research | |
| dc.description.sponsorship | Defense Threat Reduction Agency | |
| dc.format.extent | 5 p. | en_US |
| dc.identifier.citation | Deepak Chand, Chunlin He, Joseph P. Hooper, Lauren A. Mitchell, Damon A. Parrish, Jean'ne M. Shreeve, "Mono- and diiodo-triazoles and their mono nitro derivatives," Dalton Transactions, v.46 (2016), pp. 9684-9688. | en_US |
| dc.identifier.uri | https://hdl.handle.net/10945/51918 | |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.relation.ispartofseries | Faculty & Researcher Publications | |
| dc.rights | This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States. | en_US |
| dc.title | Mono- and diioso-1,2,3-trizoles and their mono nitro derivatives | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| relation.isSeriesOfPublication | c2c3de57-d1f4-47b1-aa53-6f1c074e4c20 | |
| relation.isSeriesOfPublication.latestForDiscovery | c2c3de57-d1f4-47b1-aa53-6f1c074e4c20 |
