Iodine-rich imidazolium iodate and periodate salts: en route to single-based biocidal agents
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Authors
He, Chunlin
Hooper, Joseph P.
Shreeve, Jean’ne M.
Subjects
Advisors
Date of Issue
2016
Date
Publisher
ACS Publications
Language
Abstract
Two classes of iodine-rich salts that consist of
iodine-rich cations and iodate (IO₃ˉˉ) or periodate (IO₄ˉˉ)
anions were synthesized. The synthesis of analogous I₃O₈ˉˉsalts was more difficult because of poor solubility and
hydrolytic instability. All iodine-rich salts were fully characterized
by infrared, ₁H nuclear magnetic resonance, and ₁₃C nuclear magnetic resonance spectroscopy as well as elemental
analyses. The molecular structures of compounds 15 and 24
were elucidated by X-ray single-crystal diffraction. Additionally,
the heats of formation were calculated with Gaussian 03. The
detonation properties and biocidal efficiency were calculated
and evaluated using CHEETAH 7.
Type
Article
Description
The article of record as published may be located at http://dx.doi.org/10.1021/acs.inorgchem.6b02195
Series/Report No
Department
Physics
Organization
Identifiers
NPS Report Number
Sponsors
Office of Naval Research (N00014-16-1-2089) and the Defense Threat Reduction Agency (HDTRA 1-15-1-0028).
Funding
The authors thank the M. J.
Murdock Charitable Trust, Vancouver, WA (Reference
2014120: MNL:11/20/2014), for funds to purchase a 500
MHz NMR spectrometer. We are indebted to Dr. Orion
Berryman (CHE-1337908 and CoBRE NIGMS
P20GM103546) and Dr. Richard Staples for crystal structures.
Format
Citation
Chunlin He, Joseph P. Hooper, and Jean’ne M. Shreeve, "Iodine-rich imidazolium iodate and periodate salts: en route to single-based biocidal agents." Inorg. Chem., 2016, 55 (24), pp 12844–1285;
Distribution Statement
Rights
This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.