New Generation Agent Defeat Weapons: Energetic N, N′‐Ethylene‐Bridged Polyiodoazoles
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Authors
Zhao, Gang
Kumar, Dheeraj
He, Chunlin
Hooper, Joseph P.
Imler, Gregory H.
Parrish, Damon A.
Shreeve, Jean'ne M.
Subjects
N
N′-ethylene-bridged
agent defeat weapons
energetic materials
heterocycles
polyiodoazoles
N′-ethylene-bridged
agent defeat weapons
energetic materials
heterocycles
polyiodoazoles
Advisors
Date of Issue
2017-11
Date
11/27/2017
Publisher
Wiley
Language
en_US
Abstract
Sodium salts of iodine-rich pyrazole and imida- zole with 1-(2-bromoethyl)-5-aminotetrazole are useful precursors for energetic N,N’-ethylene-bridged polyiodoa- zoles. Compounds 1–3 were characterized with IR, and 1H and 13C NMR spectroscopy as well as elemental analyses. The molecular structures of 1 and 2 were confirmed by using single crystal X-ray diffraction. Heats of formation were calculated using Gaussian 03 and detonation proper- ties and biocidal efficiency were calculated with CHEE- TAH 7. The decomposition products of 1–3 destroy microbes more effectively than some previously reported biocides since the thermal decomposition occurs at below 4008C without addition of oxidizer or combustion adjuvant.
Type
Article
Description
The article of record as published may be found at https://doi.org/10.1002/chem.201704798
Series/Report No
Department
Physics
Organization
Identifiers
NPS Report Number
Sponsors
Office of Naval Research
Defense Threat Reduction Agency
M.J. Murdock Charitable Trust
Defense Threat Reduction Agency
M.J. Murdock Charitable Trust
Funder
Financial support of the Office of Naval Research (N00014-16- 1-2089), the Defense Threat Reduction Agency (HDTRA 1-15-1- 0028), and the M. J. Murdock Charitable Trust (No. 2014120) for funds supporting the purchase of a 500 MHz NMR are gratefully acknowledged.
Format
Citation
Zhao, Gang, et al. "New Generation Agent Defeat Weapons: Energetic N, N′‐Ethylene‐Bridged Polyiodoazoles." Chemistry–A European Journal 23.66 (2017): 16753-16757.