Effects of Surface Chemistry and Crystal Size on Raman Spectra of Nanodiamond

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Authors
Mochalin, V.
Gogotsi, Y.
Osswald, S.
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Date of Issue
2012-07
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Microscopy Society of America
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Abstract
Detonation nanodiamonds (ND) exhibit exceptional properties due to their small size, rich surface chemistry, and high surface to volume ratio compared to bulk diamonds [1]. These unique characteristics also affect their Raman spectra. While for other carbon nanomaterials Raman spectroscopy is routinely used for analysis of the structure, ordering and dimensions; the presence of large amounts of non-diamond carbon, broad crystal size distributions, and numerous surface functional groups severely limit the potential of Raman spectroscopy for ND characterization due to poor understanding of their spectral features.
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Article
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The article of record as published may be found at https://doi.org/10.1017/S1431927612009592
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Department
Physics
Mechanical and Aerospace Engineering (MAE)
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Naval Postgraduate School (U.S.)
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This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.
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