The ammonation of cis-Dischlorodiamminepalladium (II)
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Authors
Atwill, James Richards
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Date of Issue
1973
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Publisher
Monterey, California. Naval Postgraduate School
Language
en_US
Abstract
The reaction of cis-dichlorodiamminepalladium(II) with ammonia: cis-Pd(NH3)2Cl2 to Pd(NH3)3Cl(+) to Pd(NH3)4(2+) Pd(NH3)4(+2) was studied over the temperature range 10-21C using ultraviolet spectroscopy. Slow and fast steps are identified and the observed rate constants for these steps were obtained. Using these values, comparisons are drawn with previously reported data.
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Thesis
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Department
Physics and Chemistry
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Approved for public release; distribution is unlimited.
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This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.