Super Dielectric Materials
Loading...
Authors
Fromille, Samuel
Phillips, Jonathan
Subjects
capacitor
dielectric
energy
dielectric
energy
Advisors
Date of Issue
2014-12-22
Date
December 22, 2014
Publisher
Language
Abstract
Evidence is provided here that a class of materials with dielectric constants greater than 10⁵ at low frequency (<10¯² Hz), herein called super dielectric materials (SDM), can be generated readily from common, inexpensive materials. Specifically it is demonstrated that high surface area alumina powders, loaded to the incipient wetness point with a solution of boric acid dissolved in water, have dielectric constants, near 0 Hz, greater than 4 × 10⁸ in all cases, a remarkable increase over the best dielectric constants previously measured for energy storage capabilities, ca. 1 × 10⁴. It is postulated that any porous, electrically insulating material (e.g., high surface area powders of silica, titania, etc.), filled with a liquid containing a high concentration of ionic species will potentially be an SDM. Capacitors created with the first generated SDM dielectrics (alumina with boric acid solution), herein called New Paradigm Super (NPS) capacitors display typical electrostatic capacitive behavior, such as increasing capacitance with decreasing thickness, and can be cycled, but are limited to a maximum effective operating voltage of about 0.8 V. A simple theory is presented: Water containing relatively high concentrations of dissolved ions saturates all, or virtually all, the pores (average diameter 500 Å) of the alumina. In an applied field the positive ionic species migrate to the cathode end, and the negative ions to the anode end of each drop. This creates giant dipoles with high charge, hence leading to high dielectric constant behavior. At about 0.8 V, water begins to break down, creating enough ionic species to “short” the individual water droplets. Potentially NPS capacitor stacks can surpass “supercapacitors” in volumetric energy density.
Type
Article
Description
The article of record as published may be found at http://dx.doi.org/10.3390/ma7128197
Series/Report No
Department
Physics
Organization
Naval Postgraduate School (U.S.)
Identifiers
NPS Report Number
Sponsors
Energy Expeditionary Office of the US Marine Corporation
Funder
Energy Expeditionary Office of the US Marine Corporation
Format
16 p.
Citation
Fromille, Samuel, and Jonathan Phillips. "Super dielectric materials." Materials 7.12 (2014): 8197-8212.
Distribution Statement
Rights
This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.