Electron paramagnetic resonance investigation of irradiated lithium acetate dihydrate and mercuric acetate single crystals
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Authors
Coneway, Clinton James.
Subjects
Lithium acetate dihydrate
Mercuric acetate
EPR
ESR
Irradiated single crystals
Radical
Mercuric acetate
EPR
ESR
Irradiated single crystals
Radical
Advisors
Tolles, William J.
Date of Issue
1971-06
Date
June 1971
Publisher
Monterey, California ; Naval Postgraduate School
Language
en_US
Abstract
An electron paramagnetic resonance study of X-ray irradiated single crystals of lithium acetate dehydrate and mercuric acetate has been made. The CH(2)CO(2) radical has been identified in lithium acetate dehydrate at liquid nitrogen temperature. The HCH angle was found to be 118(o)2 + 2.0(o). The principal elements of the hyperfine tensor and the g tensor were calculated. Mercuric acetate irradiates at liquid nitrogen temperature showed the presence of two CO(2) species. Spectra at -80 degrees C showed the presence of two CH(2)CO(2) radicals. The principal values of the hyperfine tensor for the two magnetically distinct sites were obtained.
Type
Thesis
Description
Series/Report No
Department
Department of Chemistry
Organization
Naval Postgraduate School (U.S.)
Identifiers
NPS Report Number
Sponsors
Funder
Format
Citation
Distribution Statement
Approved for public release; distribution is unlimited.
Rights
This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.