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        EPR investigation of irradiated strontium and zinc acetate single crystals

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        Author
        Tolles, W.M.
        Sanders, R.A.
        Gisch, R.G.
        Date
        1971-02-15
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        Abstract
        X-ray irradiation of strontium acetate hemihydrate produces CH3C022- and not the methyl radical as in other acetates. At higher temperatures this spectrum is replaced with two magnetically distinct ·CH2 CQ2- radicals. In the presence of the propionate. ion, further reaction proceeds at about -30°C to yield one rotamer of one magnetically distinct CHaCHCO,- radical. The ratio of propionate/acetate damage at room temperature is found to be 700: 1in strontium acetate, indicating some mechanism for the delocalization of the damage. This same reaction with a substituted propionate ion occurs in zinc acetate with a ratio of 20: 1. The coupling tensors for all species are presented.
        Description
        The article of record as published may be found at http://dx.doi.org/10.1063/1.1675050
        Rights
        This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.
        URI
        http://hdl.handle.net/10945/51487
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          Electron paramagnetic resonance investigation of irradiated lithium acetate dihydrate and mercuric acetate single crystals 

          Coneway, Clinton James. (Monterey, California ; Naval Postgraduate School, 1971);
          An electron paramagnetic resonance study of X-ray irradiated single crystals of lithium acetate dehydrate and mercuric acetate has been made. The CH(2)CO(2) radical has been identified in lithium acetate dehydrate at ...
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          Electron paramagnetic resonance study of copper halide tetrazole complexes and the free radicals in irradiated strontium acetate hemihydrate 

          Gisch, Robert Gary (Monterey, California. U.S. Naval Postgraduate School, 1969);
          An EPR study of copper halide tetrazole complexes and x-irradiated strontium acetate hemihydrate has been made. The powder spectra of some of the tetrazole complexes exhibited temperature dependent narrowing and broadening. ...
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          MgO-embedded fibre-based substrate as an effective sorbent for toxic organophosphates 

          Woo, Dong Jin; Obendorf, S. Kay (Royal Society of Chemistry, 2014);
          Magnesium oxide nanoparticles (MgO) were embedded in a cellulose acetate fibrous framework to provide self-decontaminating properties against toxic organophosphates. The concept of a co-continuous polymer blend structure ...
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