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dc.contributor.authorHemmer, James R.
dc.contributor.authorPoelma, Saemi O.
dc.contributor.authorTreat, Nicolas
dc.contributor.authorPage, Zachariah A.
dc.contributor.authorDolinski, Neil D.
dc.contributor.authorDiaz, Yvonne J.
dc.contributor.authorTomlinson, Warren
dc.contributor.authorClark, Kyle D.
dc.contributor.authorHooper, Joseph P.
dc.contributor.authorHawker, Craig
dc.contributor.authorRead de Alanis, Javier
dc.date.accessioned2017-06-01T18:59:43Z
dc.date.available2017-06-01T18:59:43Z
dc.date.issued2016
dc.identifier.citationJ.R. Hemmer, et al, "Tunable visible and near infrared photoswitches," Journal of the American Chemical Society, v.138, (2016) p. 13960-13966.en_US
dc.identifier.urihttp://hdl.handle.net/10945/53766
dc.descriptionThe article of record as published may be found at http://dx.doi.org/10.1021/jacs.6b07434en_US
dc.description.abstractA class of tunable visible and near-infrared donor−acceptor Stenhouse adduct (DASA) photoswitches were efficiently synthesized in two to four steps from commercially available starting materials with minimal purification. Using either Meldrum’s or barbituric acid “acceptors” in combination with aniline-based “donors”, an absorption range spanning from 450 to 750 nm is obtained. Additionally, photoisomerization results in complete decoloration for all adducts, yielding fully transparent, colorless solutions and films. Detailed investigations using density functional theory, nuclear magnetic resonance, and visible absorption spectroscopies provide valuable insight into the unique structure−property relationships for this novel class of photoswitches. As a final demonstration, selective photochromism is accomplished in a variety of solvents and polymer matrices, a significant advantage for applications of this new generation of DASAs.en_US
dc.description.sponsorshipNational Science Foundation (MRSEC program DMR 1121053)
dc.description.sponsorshipCalifornia NanoSystems Institute (CNSI) Challenge Grant Program
dc.format.extent7 p.en_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.en_US
dc.titleTunable visible and near infrared photoswitchesen_US
dc.typeArticleen_US
dc.contributor.corporateNaval Postgraduate School (U.S.)en_US
dc.contributor.departmentPhysicsen_US


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