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        Effects of Surface Chemistry and Crystal Size on Raman Spectra of Nanodiamond

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        Author
        Mochalin, V.
        Gogotsi, Y.
        Osswald, S.
        Date
        2012-07
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        Abstract
        Detonation nanodiamonds (ND) exhibit exceptional properties due to their small size, rich surface chemistry, and high surface to volume ratio compared to bulk diamonds [1]. These unique characteristics also affect their Raman spectra. While for other carbon nanomaterials Raman spectroscopy is routinely used for analysis of the structure, ordering and dimensions; the presence of large amounts of non-diamond carbon, broad crystal size distributions, and numerous surface functional groups severely limit the potential of Raman spectroscopy for ND characterization due to poor understanding of their spectral features.
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        The article of record as published may be found at https://doi.org/10.1017/S1431927612009592
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        http://hdl.handle.net/10945/60688
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