Show simple item record

dc.contributor.authorDeBerry, William J. Jr.
dc.contributor.authorReinhardt, Richard A.
dc.dateOctober 1, 1972
dc.date.accessioned2016-05-16T20:41:52Z
dc.date.available2016-05-16T20:41:52Z
dc.date.issued1972-10-01
dc.identifier.citationAquation kinetics of the aquoammine complexes of palladium(II) William J. DeBerry, Richard A. Reinhardt Inorg. Chem., 1972, 11 (10), pp 2401–2404en_US
dc.identifier.urihttp://hdl.handle.net/10945/48674
dc.descriptionThe article of record as published may be found at http://dx.doi.org/10.1021/ic50116a022en_US
dc.description.abstractUpon treatment with excess aqueous HClO₄, Pd(NH₃)₄²⁺ is converted through four consecutive steps to Pd(OH₂)₄²⁺. Correlation of observed rate constants with actual mechanistic steps is based primarily on reconstruction of the absorption spectra of the intermediate species; it was thus found that the rate constants decrease steadily from one step to the next. At 50°, µ = 1, rate constants found are respectively 0.020, 0.008, 9.2 X 10ˉ³ and 2.2 X 10ˉ⁴ secˉ¹. Activation enthalpies range from 21 to 24 kcal/mol and activation entropies from +4 to -4 eu. Substituent effects are compared with those in chloride-containing complexes and with those for the reverse reactions.en_US
dc.description.sponsorshipOffice of Naval Researchen_US
dc.format.extent4 p.en_US
dc.rightsThis publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.en_US
dc.titleAquation Kinetics of the Aquoammine Complexes of Palladium(II)en_US
dc.typeArticleen_US
dc.contributor.corporateNaval Postgraduate School (U.S.)en_US
dc.contributor.departmentPhysics and Chemistry


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record