Aquation Kinetics of the Aquoammine Complexes of Palladium(II)
| dc.contributor.author | DeBerry, William J. Jr. | |
| dc.contributor.author | Reinhardt, Richard A. | |
| dc.date | October 1, 1972 | |
| dc.date.accessioned | 2016-05-16T20:41:52Z | |
| dc.date.available | 2016-05-16T20:41:52Z | |
| dc.date.issued | 1972-10-01 | |
| dc.identifier.citation | Aquation kinetics of the aquoammine complexes of palladium(II) William J. DeBerry, Richard A. Reinhardt Inorg. Chem., 1972, 11 (10), pp 2401–2404 | en_US |
| dc.identifier.uri | https://hdl.handle.net/10945/48674 | |
| dc.description | The article of record as published may be found at http://dx.doi.org/10.1021/ic50116a022 | en_US |
| dc.description.abstract | Upon treatment with excess aqueous HClO₄, Pd(NH₃)₄²⁺ is converted through four consecutive steps to Pd(OH₂)₄²⁺. Correlation of observed rate constants with actual mechanistic steps is based primarily on reconstruction of the absorption spectra of the intermediate species; it was thus found that the rate constants decrease steadily from one step to the next. At 50°, µ = 1, rate constants found are respectively 0.020, 0.008, 9.2 X 10ˉ³ and 2.2 X 10ˉ⁴ secˉ¹. Activation enthalpies range from 21 to 24 kcal/mol and activation entropies from +4 to -4 eu. Substituent effects are compared with those in chloride-containing complexes and with those for the reverse reactions. | en_US |
| dc.description.sponsorship | Office of Naval Research | en_US |
| dc.format.extent | 4 p. | en_US |
| dc.rights | This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States. | en_US |
| dc.title | Aquation Kinetics of the Aquoammine Complexes of Palladium(II) | en_US |
| dc.type | Article | en_US |
| dc.contributor.corporate | Naval Postgraduate School (U.S.) | en_US |
| dc.contributor.department | Physics and Chemistry |
